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• W1997553257 abstract "Two layered indium oxalates, In(C2O4)2.5(C3N2H12)(H2O)3, I, and In(C2O4)1.5(H2O)3, II, have been hydrothermally synthesized. In I, the linkage between indium and oxalate units gives rise to a sheet with a rectangular 12-membered aperture (six indium atoms and six oxalate units). Indium atom of II has an unusual pentagonal bipyramidal coordination arrangement. The connectivity between indium and oxalate units forms a neutral puckered layer with 12- (along a-axis) and eight-membered (along b-axis) apertures. Crystal data for these two indium oxalates are as follows: I, triclinic, space group: P-1 (No. 2), a=8.725(3) Å, b=9.170(3) Å, c=9.901(3) Å, α=98.101(4)°, β=97.068(4)°, γ=102.403(4)°, V=756.3(4) Å3, Z=2, M=463.0(5), ρcalc=2.042 g/cm3, R1=0.0377, wR2=0.0834. II, monoclinic, space group: P21/c (No. 14), a=10.203(5) Å, b=6.638(1) Å, c=11.152(7) Å, β=95.649(4)°, V=751.7(4)Å3, Z=4, M=300.9(0), ρcalc=2.659 g/cm3, R1=0.0229, wR2=0.0488. TG analyses indicate the water molecules of I can be removed at 150°C. The dehydrated product retains structural integrity." @default.
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• W1997553257 date "2003-07-01" @default.
• W1997553257 modified "2023-09-23" @default.
• W1997553257 title "Hydrothermal synthesis of two layered indium oxalates with 12-membered apertures" @default.
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• W1997553257 doi "https://doi.org/10.1016/s0022-4596(03)00139-7" @default.
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