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- W1997564807 abstract "Ethylene and ethylene oxide react readily with silver clusters at 70 K to form the addition complexes, Agn(C2H4)m and Agn(C2H4O)m, respectively. The infrared photodissociation spectra of Agn(C2H4)m and Agn(C2D4)m (n=3–7) recorded in the 9–11 μm region show several characteristic vibrational bands of ethylene lying near their gas phase frequencies. Photoionization spectroscopy studies reveal that the ionization potentials (IPs) of the complexes decrease monotonically with adsorption of additional ethylene molecules. Together, these results imply that as on macroscopic silver surfaces, ethylene adsorbs molecularly to small silver clusters, with a net donation of electron density into the underlying cluster. Similarly, silver cluster–ethylene oxide complexes display IPs that decrease with increasing adsorbate coverage. The infrared depletion spectra of Agn(C2D4O)m complexes reveal a single feature at 949 cm−1, assigned to the ν4(a1) fundamental of C2D4O. These results verify that ethylene oxide adsorbs molecularly to silver clusters, with the oxygen atom oriented toward the silver cluster." @default.
- W1997564807 created "2016-06-24" @default.
- W1997564807 creator A5012677606 @default.
- W1997564807 creator A5058538163 @default.
- W1997564807 date "1997-12-22" @default.
- W1997564807 modified "2023-10-14" @default.
- W1997564807 title "The reactions of silver clusters with ethylene and ethylene oxide: Infrared and photoionization studies of Agn(C2H4)m, Agn(C2H4O)m and their deuterated analogs" @default.
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- W1997564807 doi "https://doi.org/10.1063/1.474219" @default.
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