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- W1997580655 abstract "Cp∗Ir(η5-2,5-Me2T)2+ (1), where Cp∗ = η5-C5Me5 and 2,5-Me2T = 2,5-dimethylthiophene, reacts with PhLi to give Cp∗Ir(2,5-Me2T·2Ph) and the acylthiolate Cp∗Ir(η4-SC3H2MeC(=O)Me) (3) which incorporates oxygen from the tetrahydrofuran solvent and whose structure was established crystallographically. The analogous reaction of 1 with MeLi gives Cp∗Ir(2,5-Me2T · 2Me). Complex 1 reacts with −CH(CO2Me)2 to give Cp∗Ir(η4-2,5-Me2T · C(CO2Me)2) (6), which contains an opened-ring thiolate ligand. With OH−, 1 gives both 3 and Cp∗Ir(η4-2,5-Me2T · O) (7), which incorporates a thiophene S-oxide ligand. These reactions are discussed in the context of related reactions of η5-thiophene complexes in the literature." @default.
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- W1997580655 date "1996-04-01" @default.
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- W1997580655 title "Reactions of the η5-2,5-dimethylthiophene complex Cp∗Ir(η5-2,5-Me2T)2+ with nucleophiles (Ph−, Me−, −CH(CO2Me)2 and OH−)1" @default.
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- W1997580655 doi "https://doi.org/10.1016/0022-328x(95)06031-q" @default.
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