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- W1997580863 abstract "Abstract The pressure and temperature dependence of the rate of 18O exchange in feldspars can be interpreted kinetically in terms of a two-stage process, i.e. a surface reaction which in most cases is fast compared with the rate-determining diffusion step which follows it. Published measurements gave apparently contradictory results for the pressure dependence but can be reconciled if account is taken of the change in density of water with pressure, and then show that there is little effect of pressure on the diffusion constant in the solid. The proposed kinetic model can account for the narrow range of energies of activation for diffusion of oxygen in hydrothermal systems and for hydrogen in hydrous minerals. The previously noted unusual change of activation energy with temperature observed for hydrogen diffusion in epidote can also be interpreted." @default.
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- W1997580863 date "1985-06-01" @default.
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- W1997580863 title "The effect of pressure on oxygen isotope exchange in silicates" @default.
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- W1997580863 doi "https://doi.org/10.1016/0009-2541(85)90154-8" @default.
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