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• W1997609909 abstract "Both end-functionalized (alpha-bromo and omega-carboxy) compounds were first tested for the radical reaction on the silicon-hydride (Si-H) terminated porous silicon (PSi) with/without the presence of diacyl peroxide initiator under microwave irradiation. Then the carboxylic acid monolayers (CAMs) assembled on PSi through the robust Si-C bonds were converted to amino-reactive linker, N-hydroxysuccinimide (NHS)-ester, terminated monolayers. And finally two proteins of bovine serum albumin (BSA) and lysozyme (Lys) were immobilized through amide bonds. The optimum PSi membrane for protein immobilization without collapse, with parameters of porous radii 4-10 nm and depth 0.2-4.6 mum, was prepared from the (100)-oriented p-type silicon wafer. The chemically converted surface products were monitored with Fourier transform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS), and field emission scanning electron microscopy (FESEM)." @default.
• W1997609909 created "2016-06-24" @default.
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• W1997609909 date "2005-10-04" @default.
• W1997609909 modified "2023-10-17" @default.
• W1997609909 title "Reaction of Porous Silicon with Both End-Functionalized Organic Compounds Bearing α-Bromo and ω-Carboxy Groups for Immobilization of Biomolecules" @default.
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• W1997609909 doi "https://doi.org/10.1021/jp0535689" @default.
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