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• W1997622681 abstract "Abstract We report measurements of the water content and swelling of wet‐spun films of Na‐, K‐, Rb‐, and Cs‐DNA as a function of relative humidity (rh). The water contents (number of water molecules per base pair of DNA) of these films are found to be quite similar, indicating that the identity of the counterion species is unimportant for the water content. Since the A to B transition for these DNAs occurs at different rhs, the corresponding water contents of the A to B transition are found to be quite different. These films swell as a function of rh in a very similar manner, implying that the changes in the intermolecular bonds in the different DNAs are similar. Dramatic changes are observed in the dimensions of the films above 84% rh for all types of DNA. Combining the water content and swelling measurements yields the dependence of the volume per base pair on water content. The volume per base pair is observed to be a nonlinear function of water content, indicating nonideal mixing of the water with the DNA." @default.
• W1997622681 created "2016-06-24" @default.
• W1997622681 creator A5019410937 @default.
• W1997622681 creator A5039384391 @default.
• W1997622681 creator A5059987394 @default.
• W1997622681 date "1990-01-01" @default.
• W1997622681 modified "2023-10-18" @default.
• W1997622681 title "Counterion effects on the physical properties and the A to B transition of calf‐thymus DNA films" @default.
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• W1997622681 doi "https://doi.org/10.1002/bip.360300903" @default.
• W1997622681 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/2092817" @default.
• W1997622681 hasPublicationYear "1990" @default.
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