FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1997631404> ?p ?o ?g. }

• W1997631404 endingPage "7788" @default.
• W1997631404 startingPage "7782" @default.
• W1997631404 abstract "Solvothermal reactions with different solvents produced two iron trimesates [Fe2(H2O)2(BTC)4/3]Cl x 4.5(DMF) (1) and [Fe4Cl(BTC)8/3]Cl2 x H2O x 2.5(DEF) (2) (BTC = 1,3,5-benzenetricarboxylate, DMF = N,N'-dimethylformamide, DEF = N,N'-diethylformamide). The framework of 1 is a (3,4)-connected net constructed from mixed-valence paddlewheel Fe2(II, III) units and BTC linkers, while the framework of 2 is a (3,8)-connected net built from mixed-valence square-planar Fe4(III, III, III, II) units and BTC linkers. The large volume inside the framework of 1 (or 2) is occupied by disordered Cl- anions and guest DMF (or DEF) molecules. The mixed-valence character of the frameworks of 1 and 2 was confirmed by Mössbauer spectroscopy studies. The active electronic property of iron cations may be the origin of the variability of the iron-organic frameworks, which are readily affected by some synthetic factors, such as solvents. Magnetic studies reveal that there are antiferromagnetic exchange interactions among the Fe atoms in 1 and 2. Ion-exchange studies for 1 show that the Cl- anions inside the framework of 1 can be exchanged by CNS- anions." @default.
• W1997631404 created "2016-06-24" @default.
• W1997631404 creator A5013189975 @default.
• W1997631404 creator A5015901909 @default.
• W1997631404 creator A5019491962 @default.
• W1997631404 creator A5025365134 @default.
• W1997631404 creator A5069009550 @default.
• W1997631404 creator A5087949054 @default.
• W1997631404 creator A5089508521 @default.
• W1997631404 date "2007-08-15" @default.
• W1997631404 modified "2023-10-11" @default.
• W1997631404 title "Mixed-Valence Iron(II, III) Trimesates with Open Frameworks Modulated by Solvents" @default.
• W1997631404 cites W1957222199 @default.
• W1997631404 cites W1971858674 @default.
• W1997631404 cites W1974984972 @default.
• W1997631404 cites W1977276854 @default.
• W1997631404 cites W1979295139 @default.
• W1997631404 cites W1992612523 @default.
• W1997631404 cites W1996427836 @default.
• W1997631404 cites W1999908724 @default.
• W1997631404 cites W1999937609 @default.
• W1997631404 cites W2008708346 @default.
• W1997631404 cites W2015461642 @default.
• W1997631404 cites W2046522844 @default.
• W1997631404 cites W2047024367 @default.
• W1997631404 cites W2048443746 @default.
• W1997631404 cites W2050072245 @default.
• W1997631404 cites W2051853320 @default.
• W1997631404 cites W2053272293 @default.
• W1997631404 cites W2056252713 @default.
• W1997631404 cites W2064241753 @default.
• W1997631404 cites W2067053065 @default.
• W1997631404 cites W2067743341 @default.
• W1997631404 cites W2082897861 @default.
• W1997631404 cites W2089065219 @default.
• W1997631404 cites W2089562522 @default.
• W1997631404 cites W2102363490 @default.
• W1997631404 cites W2105218596 @default.
• W1997631404 cites W2105628674 @default.
• W1997631404 cites W2132004108 @default.
• W1997631404 cites W2411648892 @default.
• W1997631404 cites W2891670902 @default.
• W1997631404 cites W4254171224 @default.
• W1997631404 cites W974065102 @default.
• W1997631404 doi "https://doi.org/10.1021/ic062273m" @default.
• W1997631404 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/17696421" @default.
• W1997631404 hasPublicationYear "2007" @default.
• W1997631404 type Work @default.
• W1997631404 sameAs 1997631404 @default.
• W1997631404 citedByCount "111" @default.
• W1997631404 countsByYear W19976314042012 @default.
• W1997631404 countsByYear W19976314042013 @default.
• W1997631404 countsByYear W19976314042014 @default.
• W1997631404 countsByYear W19976314042015 @default.
• W1997631404 countsByYear W19976314042016 @default.
• W1997631404 countsByYear W19976314042017 @default.
• W1997631404 countsByYear W19976314042018 @default.
• W1997631404 countsByYear W19976314042019 @default.
• W1997631404 countsByYear W19976314042020 @default.
• W1997631404 countsByYear W19976314042021 @default.
• W1997631404 countsByYear W19976314042022 @default.
• W1997631404 countsByYear W19976314042023 @default.
• W1997631404 crossrefType "journal-article" @default.
• W1997631404 hasAuthorship W1997631404A5013189975 @default.
• W1997631404 hasAuthorship W1997631404A5015901909 @default.
• W1997631404 hasAuthorship W1997631404A5019491962 @default.
• W1997631404 hasAuthorship W1997631404A5025365134 @default.
• W1997631404 hasAuthorship W1997631404A5069009550 @default.
• W1997631404 hasAuthorship W1997631404A5087949054 @default.
• W1997631404 hasAuthorship W1997631404A5089508521 @default.
• W1997631404 hasConcept C121332964 @default.
• W1997631404 hasConcept C145148216 @default.
• W1997631404 hasConcept C155355069 @default.
• W1997631404 hasConcept C168900304 @default.
• W1997631404 hasConcept C178790620 @default.
• W1997631404 hasConcept C179104552 @default.
• W1997631404 hasConcept C185592680 @default.
• W1997631404 hasConcept C26873012 @default.
• W1997631404 hasConcept C2777712214 @default.
• W1997631404 hasConcept C2780471494 @default.
• W1997631404 hasConcept C32891209 @default.
• W1997631404 hasConcept C32909587 @default.
• W1997631404 hasConcept C62520636 @default.
• W1997631404 hasConcept C70854507 @default.
• W1997631404 hasConcept C8010536 @default.
• W1997631404 hasConceptScore W1997631404C121332964 @default.
• W1997631404 hasConceptScore W1997631404C145148216 @default.
• W1997631404 hasConceptScore W1997631404C155355069 @default.
• W1997631404 hasConceptScore W1997631404C168900304 @default.
• W1997631404 hasConceptScore W1997631404C178790620 @default.
• W1997631404 hasConceptScore W1997631404C179104552 @default.
• W1997631404 hasConceptScore W1997631404C185592680 @default.
• W1997631404 hasConceptScore W1997631404C26873012 @default.
• W1997631404 hasConceptScore W1997631404C2777712214 @default.
• W1997631404 hasConceptScore W1997631404C2780471494 @default.
• W1997631404 hasConceptScore W1997631404C32891209 @default.
• W1997631404 hasConceptScore W1997631404C32909587 @default.
• W1997631404 hasConceptScore W1997631404C62520636 @default.

• next