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• W1997656489 abstract "Hydrogenation of CO2 to hydrocarbons over iron catalysts reduced with hydrogen at 350°C and 500°C has been compared with that of CO. The space time yield of hydrocarbons from CO2 at 250°C is significantly lower than from CO and the selectivity to olefin compounds is also lower from CO2. During the reaction with CO, χ-Fe2.2C is formed, and the surface, which is oxidized even after the reduction at 500°C, is further reduced. On the other hand, formation of the carbide species is slight in hydrogenation of CO2 while the surface is rather oxidized. The formation of the carbide species, which is probably the active site of hydrocarbon formation, is suppressed in the presence of CO2." @default.
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• W1997656489 date "2000-03-01" @default.
• W1997656489 modified "2023-09-26" @default.
• W1997656489 title "A comparative study on hydrogenation of carbon dioxide and carbon monoxide over iron catalyst" @default.
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• W1997656489 doi "https://doi.org/10.1016/s1381-1169(99)00359-3" @default.
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