Matches in SemOpenAlex for { <https://semopenalex.org/work/W1997658522> ?p ?o ?g. }
- W1997658522 endingPage "759" @default.
- W1997658522 startingPage "749" @default.
- W1997658522 abstract "The challenge of achieving selective and predictable functionalizations at C−H bonds with complex poly(hetero)aromatic substrates was addressed by two different approaches. Site-selectivity can be obtained by applying various reaction conditions that are (hetero)arene specific to substrates that contain indoles, pyridine N-oxide, and polyfluorinated benzenes. An experimental classification of electron-rich heteroarenes based on their reactivity toward palladium-catalyzed C−H functionalization was established, the result of which correlated well with the order of reactivity predicted by the DFT-calculated concerted metalation−deprotonation (CMD) pathway. Model substrates containing two reactive heteroarenes were then reacted under general reaction conditions to demonstrate the applicability this reactivity chart in predicting the regioselectivity of the palladium-catalyzed direct arylation and benzylation reactions." @default.
- W1997658522 created "2016-06-24" @default.
- W1997658522 creator A5018004877 @default.
- W1997658522 creator A5059338659 @default.
- W1997658522 creator A5070976856 @default.
- W1997658522 creator A5079969045 @default.
- W1997658522 creator A5090861846 @default.
- W1997658522 date "2010-12-01" @default.
- W1997658522 modified "2023-10-09" @default.
- W1997658522 title "Predictable and Site-Selective Functionalization of Poly(hetero)arene Compounds by Palladium Catalysis" @default.
- W1997658522 cites W1972836172 @default.
- W1997658522 cites W1974115964 @default.
- W1997658522 cites W1980934047 @default.
- W1997658522 cites W1982230863 @default.
- W1997658522 cites W1984703406 @default.
- W1997658522 cites W1987207730 @default.
- W1997658522 cites W1990116902 @default.
- W1997658522 cites W1990725984 @default.
- W1997658522 cites W1992766570 @default.
- W1997658522 cites W2000501946 @default.
- W1997658522 cites W2007375066 @default.
- W1997658522 cites W2011421576 @default.
- W1997658522 cites W2011802953 @default.
- W1997658522 cites W2015520068 @default.
- W1997658522 cites W2016755677 @default.
- W1997658522 cites W2017384210 @default.
- W1997658522 cites W2020278286 @default.
- W1997658522 cites W2023345000 @default.
- W1997658522 cites W2027600077 @default.
- W1997658522 cites W2028824397 @default.
- W1997658522 cites W2031556326 @default.
- W1997658522 cites W2038814936 @default.
- W1997658522 cites W2038974680 @default.
- W1997658522 cites W2052948087 @default.
- W1997658522 cites W2058476328 @default.
- W1997658522 cites W2061328782 @default.
- W1997658522 cites W2066176194 @default.
- W1997658522 cites W2071418326 @default.
- W1997658522 cites W2073962375 @default.
- W1997658522 cites W2078442327 @default.
- W1997658522 cites W2096021030 @default.
- W1997658522 cites W2097184152 @default.
- W1997658522 cites W2104177340 @default.
- W1997658522 cites W2120644129 @default.
- W1997658522 cites W2125014016 @default.
- W1997658522 cites W2132920966 @default.
- W1997658522 cites W2135247040 @default.
- W1997658522 cites W2135915477 @default.
- W1997658522 cites W2145662716 @default.
- W1997658522 cites W2146953384 @default.
- W1997658522 cites W2152083435 @default.
- W1997658522 cites W2163796127 @default.
- W1997658522 cites W2167028958 @default.
- W1997658522 cites W2466897053 @default.
- W1997658522 cites W2950206052 @default.
- W1997658522 cites W2950338620 @default.
- W1997658522 cites W2951119974 @default.
- W1997658522 cites W2951399378 @default.
- W1997658522 doi "https://doi.org/10.1021/jo102081a" @default.
- W1997658522 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/21117710" @default.
- W1997658522 hasPublicationYear "2010" @default.
- W1997658522 type Work @default.
- W1997658522 sameAs 1997658522 @default.
- W1997658522 citedByCount "145" @default.
- W1997658522 countsByYear W19976585222012 @default.
- W1997658522 countsByYear W19976585222013 @default.
- W1997658522 countsByYear W19976585222014 @default.
- W1997658522 countsByYear W19976585222015 @default.
- W1997658522 countsByYear W19976585222016 @default.
- W1997658522 countsByYear W19976585222017 @default.
- W1997658522 countsByYear W19976585222018 @default.
- W1997658522 countsByYear W19976585222019 @default.
- W1997658522 countsByYear W19976585222020 @default.
- W1997658522 countsByYear W19976585222021 @default.
- W1997658522 countsByYear W19976585222022 @default.
- W1997658522 countsByYear W19976585222023 @default.
- W1997658522 crossrefType "journal-article" @default.
- W1997658522 hasAuthorship W1997658522A5018004877 @default.
- W1997658522 hasAuthorship W1997658522A5059338659 @default.
- W1997658522 hasAuthorship W1997658522A5070976856 @default.
- W1997658522 hasAuthorship W1997658522A5079969045 @default.
- W1997658522 hasAuthorship W1997658522A5090861846 @default.
- W1997658522 hasConcept C115537861 @default.
- W1997658522 hasConcept C118629725 @default.
- W1997658522 hasConcept C118792377 @default.
- W1997658522 hasConcept C142724271 @default.
- W1997658522 hasConcept C145148216 @default.
- W1997658522 hasConcept C147789679 @default.
- W1997658522 hasConcept C161790260 @default.
- W1997658522 hasConcept C178790620 @default.
- W1997658522 hasConcept C185592680 @default.
- W1997658522 hasConcept C204787440 @default.
- W1997658522 hasConcept C21951064 @default.
- W1997658522 hasConcept C2775855785 @default.
- W1997658522 hasConcept C2776910235 @default.
- W1997658522 hasConcept C2779485729 @default.
- W1997658522 hasConcept C502130503 @default.
- W1997658522 hasConcept C59759590 @default.