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- W1997700735 abstract "De Wolff disorder, microtwinning, and point defects which are characteristic for γ-MnO2 have been studied using molecular modeling. Particular attention was paid to the effects these defects have on the X-ray diffraction (XRD) pattern. Comparisons with observed XRD patterns allow identification of structural features in chemical (CMD) and electrochemical (EMD) manganese dioxide. The major factor determining the structure of γ-MnO2 is de Wolff disorder. CMD materials are characterized by a larger percentage of pyrolusite while EMD materials contain more ramsdellite. Microtwinning occurs to a larger extent in EMD than in CMD materials. EMD materials are also higher in energy." @default.
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- W1997700735 date "2004-01-01" @default.
- W1997700735 modified "2023-10-16" @default.
- W1997700735 title "Understanding γ-MnO2 by molecular modeling" @default.
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- W1997700735 doi "https://doi.org/10.1016/s0022-4596(03)00393-1" @default.
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