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- W1997735010 abstract "Optically active α- and α,β-substituted aldehyde hydrazones 2, 4, and 7, which are readily available by asymmetric alkylation. Michael addition or [2,3]-Wittig rearrangement of chiral hydrazones can be transformed into nitriles 3 and 5 or cyanohydrins 8 by MMPP mediated oxidation, respectively. This synthetic sequence offers a C-C connective entry into optically active functionalised nitriles with good overall yields (30—75 %) together with high diastereo- and enantioselectivities (de = 76-≥ 96%. ee72- ≥97%)." @default.
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- W1997735010 date "1995-09-01" @default.
- W1997735010 modified "2023-10-18" @default.
- W1997735010 title "Asymmetric synthesis of α-substituted nitriles and cyanohydrins by oxidative cleavage of chiral aldehyde hydrazones with magnesium monoperoxyphthalate" @default.
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- W1997735010 doi "https://doi.org/10.1016/0040-4020(95)00647-q" @default.
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