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- W1997767269 abstract "Abstract The temperature dependence of the 81 Br NQR frequencies (v D ) for uncoordinated Br - ions in trans-[CoBr 2 (en) 2 ] [D 5 O 2 ]Br 2 (D) has been determined by a continuous-wave spectrometer. v D amounted to 16.200 MHz at 273 K. This is lower by 418 kHz than the 81 Br NQR frequency (v H ) for trans-[CoBr 2 (en 2 ] [H 5 O 2 ]Br 2 (H). The frequency difference (Δv = v H -v D ) remained almost constant in the temperature range studied. A shortening of the O-H bond length caused by deuteration could explain the magnitude and the sign of Av on the basis of a point charge model calculation. The compounds D and H yielded 81Br NQR lines in the range 110-320 K and 90-343 K, respectively. As to the 59 Co NQR frequencies (7/2 - 5/2), the observed isotope frequency shifts (Δv 1 = v 1H - v 1D ) between D and H were smaller than 5 kHz. Below 160 K, 59 Co resonances were only available by pulsed experiments. 59 Co NQR spin-lattice relaxation times T 1Q of 0.54 ms at 194 K and 4.8 s at 77 K for H have been observed." @default.
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- W1997767269 date "1994-02-01" @default.
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- W1997767269 title "<sup>81</sup>Br NQR for Uncoordinated Br ions in trans-[CoBr<sub>2</sub>(en)<sub>2</sub>][H<sub>5</sub>O<sub>2</sub>]Br<sub>2</sub> and trans-[CoBr<sub>2</sub>(en)<sub>2</sub>] [D<sub>5</sub>O<sub>2</sub>]Br<sub>2</sub>" @default.
- W1997767269 doi "https://doi.org/10.1515/zna-1994-1-232" @default.
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