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- W1997777108 abstract "Adsorption of poly(oxyethylene) of nine different molecular weights ranging from 194 to 2.49×106 from aqueous solution of 100 mg/l on activated carbons was tried in a batch finite bath. Activated carbon of coconut shell base, which has micropores of 8 A radius, and of lignite base activated carbon showed a reasonable capacity of adsorption of even poly(oxyethylene) of molecular weight bigger than 104 which has Flory''s dimension of 84 A radius. This suggests that shrinkage of a polymer molecule occurs when it is adsorbed on the carbon surface. As for the rate of adsorption, surface diffusion possibly caused by migration of monomer units is considered dominant, and the effective surface diffusion coefficient was determined for each system by applying the concentration diagrams previously presented by the authors. The effective surface diffusion coefficient on each carbon decreased in proportion to the square root of molecular weight of the polymer." @default.
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- W1997777108 title "Adsorption of poly(oxyethylene) of various molecular weights from aqueous solutions on activated carbon." @default.
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