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- W1997788396 abstract "Abstract In the reaction of N,N'-bis-trimethylsilyl-dimethylurea with As[N(CH 3 ) 2 ] 3 a four membered ring O = C(NCH 3 ) 2 AsN(CH 3 ) 2 1 could be isolated. 1 was not obtained by cleavage of the Si-N-bonds with the corresponding chloride. In contrast CH 3 N[CONCH 3 Si(CH 3 ) 3 ] 2 reacts with AsCb to yield the six-membered ring CH 3 N(CON-CH 3 ) 2 ASCl 2. The four-membered ring which contains an arsenic-halogen bond seems to be unstable. In the adamantane-type compound, AS 4 (NCH 3 ) 6 , one methylamine could be eliminated by CF 3 SO 3 H to give AS 4 (NCH 3 ) 5 (OSO 2 CF 3 ) 2 3. 1 H, 19 F NMR as well as mass spectroscopy have been used in the characterization of the products obtained." @default.
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- W1997788396 date "1978-07-01" @default.
- W1997788396 modified "2023-09-23" @default.
- W1997788396 title "Arsenhaltige Heterocyclen / Heterocycles Containing Arsenic" @default.
- W1997788396 doi "https://doi.org/10.1515/znb-1978-0715" @default.
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