Matches in SemOpenAlex for { <https://semopenalex.org/work/W1997804985> ?p ?o ?g. }
Showing items 1 to 63 of
63
with 100 items per page.
- W1997804985 abstract "The reaction of uranium oxides and chlorine to prepare anhydrous uranium tetrachloride (UCl{sub 4}) are important to more economical preparation of uranium metal. The most practical reactions require carbon or carbon monoxide (CO) to give CO or carbon dioxide (CO{sub 2}) as waste gases. The chemistry of U-O-Cl compounds is very complex with valances of 3, 4, 5, and 6 and with stable oxychlorides. Literature was reviewed to collect thermochemical data, phase equilibrium information, and results of experimental studies. Calculations using thermodynamic data can identify the probable reactions, but the results are uncertain. All the U-O-Cl compounds have large free energies of formation and the calculations give uncertain small differences of large numbers. The phase diagram for UCl{sub 4}-UO{sub 2} shows a reaction to form uranium oxychloride (UOCl{sub 2}) that has a good solubility in molten UCl{sub 4}. This appears more favorable to good rates of reaction than reaction of solids and gases. There is limited information on U-O-Cl salt properties. Information on the preparation of titanium, zirconium, silicon, and thorium tetrachlorides (TiCl{sub 4}, ZrCl{sub 4}, SiCl{sub 4}, ThCl{sub 4}) by reaction of oxides with chlorine (Cl{sub 2}) and carbon has application to the preparation of UCl{sub 4}." @default.
- W1997804985 created "2016-06-24" @default.
- W1997804985 creator A5031877687 @default.
- W1997804985 date "1992-02-01" @default.
- W1997804985 modified "2023-09-23" @default.
- W1997804985 title "Literature information applicable to the reaction of uranium oxides with chlorine to prepare uranium tetrachloride" @default.
- W1997804985 cites W182502242 @default.
- W1997804985 cites W1995991520 @default.
- W1997804985 cites W2073323666 @default.
- W1997804985 cites W58643809 @default.
- W1997804985 doi "https://doi.org/10.2172/10127689" @default.
- W1997804985 hasPublicationYear "1992" @default.
- W1997804985 type Work @default.
- W1997804985 sameAs 1997804985 @default.
- W1997804985 citedByCount "0" @default.
- W1997804985 crossrefType "report" @default.
- W1997804985 hasAuthorship W1997804985A5031877687 @default.
- W1997804985 hasBestOaLocation W19978049852 @default.
- W1997804985 hasConcept C161790260 @default.
- W1997804985 hasConcept C178790620 @default.
- W1997804985 hasConcept C179104552 @default.
- W1997804985 hasConcept C185592680 @default.
- W1997804985 hasConcept C187714232 @default.
- W1997804985 hasConcept C191897082 @default.
- W1997804985 hasConcept C192562407 @default.
- W1997804985 hasConcept C2777359374 @default.
- W1997804985 hasConcept C505241676 @default.
- W1997804985 hasConcept C512735826 @default.
- W1997804985 hasConcept C527038400 @default.
- W1997804985 hasConcept C534791751 @default.
- W1997804985 hasConcept C555451288 @default.
- W1997804985 hasConceptScore W1997804985C161790260 @default.
- W1997804985 hasConceptScore W1997804985C178790620 @default.
- W1997804985 hasConceptScore W1997804985C179104552 @default.
- W1997804985 hasConceptScore W1997804985C185592680 @default.
- W1997804985 hasConceptScore W1997804985C187714232 @default.
- W1997804985 hasConceptScore W1997804985C191897082 @default.
- W1997804985 hasConceptScore W1997804985C192562407 @default.
- W1997804985 hasConceptScore W1997804985C2777359374 @default.
- W1997804985 hasConceptScore W1997804985C505241676 @default.
- W1997804985 hasConceptScore W1997804985C512735826 @default.
- W1997804985 hasConceptScore W1997804985C527038400 @default.
- W1997804985 hasConceptScore W1997804985C534791751 @default.
- W1997804985 hasConceptScore W1997804985C555451288 @default.
- W1997804985 hasLocation W19978049851 @default.
- W1997804985 hasLocation W19978049852 @default.
- W1997804985 hasLocation W19978049853 @default.
- W1997804985 hasOpenAccess W1997804985 @default.
- W1997804985 hasPrimaryLocation W19978049851 @default.
- W1997804985 hasRelatedWork W1969035359 @default.
- W1997804985 hasRelatedWork W1993279681 @default.
- W1997804985 hasRelatedWork W2045144792 @default.
- W1997804985 hasRelatedWork W2059151363 @default.
- W1997804985 hasRelatedWork W2071668195 @default.
- W1997804985 hasRelatedWork W2266434633 @default.
- W1997804985 hasRelatedWork W2299174175 @default.
- W1997804985 hasRelatedWork W3010183313 @default.
- W1997804985 hasRelatedWork W4244658533 @default.
- W1997804985 hasRelatedWork W4253356949 @default.
- W1997804985 isParatext "false" @default.
- W1997804985 isRetracted "false" @default.
- W1997804985 magId "1997804985" @default.
- W1997804985 workType "report" @default.