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- W1997804987 abstract "Two tetrabromocuprate(II) complexes containing substituted benzyl alkyl pyridinium, [Bz-4-MePy]2[CuBr4] (1) and [Bz-4-EtPy]2[CuBr4] (2) ([Bz-4MePy]+ = (1-benzyl-4′-methylpyridinium) [Bz-4-EtPy]+ = 1-benzyl-4′-ethylpyridinium), were crystallized from methanol and dilute HBr solutions, and were determined by single crystal X-ray diffraction. Two complexes crystallize in the orthorhombic system with space group Pna21, and comprise two tortuous cations and one tetrahedral [CuBr4]2– anion. The [CuBr4]2– anions in two complexes form a linear chain by Br···Br interaction with the distance of 4.001 A for 1 and 4.062 A for 2, while the combination of C‒H···Br and C‒H···N weak hydrogen bonds, p···π and π···π, interactions consolidate the crystal packing and results in a 3D network structure." @default.
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- W1997804987 date "2014-02-25" @default.
- W1997804987 modified "2023-10-16" @default.
- W1997804987 title "Syntheses, Weak Interactions, and Crystal Structures of Two Tetrabromocuprate(II) Complexes Containing Benzyl Substituted Alkyl Pyridinium" @default.
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- W1997804987 doi "https://doi.org/10.1080/15533174.2013.790058" @default.
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