Matches in SemOpenAlex for { <https://semopenalex.org/work/W1997884356> ?p ?o ?g. }
Showing items 1 to 91 of
91
with 100 items per page.
- W1997884356 endingPage "369" @default.
- W1997884356 startingPage "349" @default.
- W1997884356 abstract "Abstract Alkylmercuric benzoate and chloride formed in the benzoyl peroxide-initiated reaction of dialkylmercury in carbon tetrachloride solutions arise by homolytic displacements. Kinetic isotope effects demonstrate that any alkylmercuri radicals formed in the concurrent reductive elimination to metallic mercury cannot be intermediates leading to alkylmercuric chloride. Benzoyl peroxide and butyryl peroxide show widely divergent behavior as initiators owing to differences in the stabilities of the acyloxy radicals formed on homolysis, the relatively long-lived benzoyloxy radical being effective in S H 2 displacements on dialkylmercury in contrast to propyl radicals derived from the highly unstable butyryloxy radicals. The reactivity of oxygen-centered, chlorine and alkyl radicals are compared in homolytic displacements. A unified mechanism is presented for reductive elimination and the various substitution processes observed concurrently in dialkylmercury compounds, in which the radical intermediates are shared in common." @default.
- W1997884356 created "2016-06-24" @default.
- W1997884356 creator A5030343286 @default.
- W1997884356 creator A5065318916 @default.
- W1997884356 date "1977-01-01" @default.
- W1997884356 modified "2023-09-26" @default.
- W1997884356 title "Organomercurials. II. Substitution processes in the homolytic cleavage of dialkylmercury the formation of alkylmercury(II) derivatives" @default.
- W1997884356 cites W1525923171 @default.
- W1997884356 cites W1963919070 @default.
- W1997884356 cites W1971861124 @default.
- W1997884356 cites W1975259364 @default.
- W1997884356 cites W1989845335 @default.
- W1997884356 cites W1998446750 @default.
- W1997884356 cites W2006430420 @default.
- W1997884356 cites W2012763484 @default.
- W1997884356 cites W2027212827 @default.
- W1997884356 cites W2030083947 @default.
- W1997884356 cites W2038203145 @default.
- W1997884356 cites W2064299064 @default.
- W1997884356 cites W2067602389 @default.
- W1997884356 cites W2076890368 @default.
- W1997884356 cites W2079657050 @default.
- W1997884356 cites W2113396360 @default.
- W1997884356 cites W2166905329 @default.
- W1997884356 cites W2312335439 @default.
- W1997884356 cites W2315247356 @default.
- W1997884356 cites W2318897204 @default.
- W1997884356 cites W2321406582 @default.
- W1997884356 cites W2330519728 @default.
- W1997884356 cites W2950981020 @default.
- W1997884356 doi "https://doi.org/10.1016/s0022-328x(00)92597-x" @default.
- W1997884356 hasPublicationYear "1977" @default.
- W1997884356 type Work @default.
- W1997884356 sameAs 1997884356 @default.
- W1997884356 citedByCount "12" @default.
- W1997884356 crossrefType "journal-article" @default.
- W1997884356 hasAuthorship W1997884356A5030343286 @default.
- W1997884356 hasAuthorship W1997884356A5065318916 @default.
- W1997884356 hasConcept C111185830 @default.
- W1997884356 hasConcept C127413603 @default.
- W1997884356 hasConcept C139066938 @default.
- W1997884356 hasConcept C155647269 @default.
- W1997884356 hasConcept C161790260 @default.
- W1997884356 hasConcept C175156509 @default.
- W1997884356 hasConcept C175689099 @default.
- W1997884356 hasConcept C178790620 @default.
- W1997884356 hasConcept C185592680 @default.
- W1997884356 hasConcept C187320778 @default.
- W1997884356 hasConcept C199360897 @default.
- W1997884356 hasConcept C2778220771 @default.
- W1997884356 hasConcept C3044715 @default.
- W1997884356 hasConcept C41008148 @default.
- W1997884356 hasConcept C43369102 @default.
- W1997884356 hasConcept C71240020 @default.
- W1997884356 hasConceptScore W1997884356C111185830 @default.
- W1997884356 hasConceptScore W1997884356C127413603 @default.
- W1997884356 hasConceptScore W1997884356C139066938 @default.
- W1997884356 hasConceptScore W1997884356C155647269 @default.
- W1997884356 hasConceptScore W1997884356C161790260 @default.
- W1997884356 hasConceptScore W1997884356C175156509 @default.
- W1997884356 hasConceptScore W1997884356C175689099 @default.
- W1997884356 hasConceptScore W1997884356C178790620 @default.
- W1997884356 hasConceptScore W1997884356C185592680 @default.
- W1997884356 hasConceptScore W1997884356C187320778 @default.
- W1997884356 hasConceptScore W1997884356C199360897 @default.
- W1997884356 hasConceptScore W1997884356C2778220771 @default.
- W1997884356 hasConceptScore W1997884356C3044715 @default.
- W1997884356 hasConceptScore W1997884356C41008148 @default.
- W1997884356 hasConceptScore W1997884356C43369102 @default.
- W1997884356 hasConceptScore W1997884356C71240020 @default.
- W1997884356 hasIssue "3" @default.
- W1997884356 hasLocation W19978843561 @default.
- W1997884356 hasOpenAccess W1997884356 @default.
- W1997884356 hasPrimaryLocation W19978843561 @default.
- W1997884356 hasRelatedWork W1551955150 @default.
- W1997884356 hasRelatedWork W1844357946 @default.
- W1997884356 hasRelatedWork W1971045472 @default.
- W1997884356 hasRelatedWork W2024662799 @default.
- W1997884356 hasRelatedWork W2032486288 @default.
- W1997884356 hasRelatedWork W2071117972 @default.
- W1997884356 hasRelatedWork W2340027044 @default.
- W1997884356 hasRelatedWork W4241693846 @default.
- W1997884356 hasRelatedWork W4244358402 @default.
- W1997884356 hasRelatedWork W1506292215 @default.
- W1997884356 hasVolume "124" @default.
- W1997884356 isParatext "false" @default.
- W1997884356 isRetracted "false" @default.
- W1997884356 magId "1997884356" @default.
- W1997884356 workType "article" @default.