Matches in SemOpenAlex for { <https://semopenalex.org/work/W1997894511> ?p ?o ?g. }
- W1997894511 endingPage "5629" @default.
- W1997894511 startingPage "5622" @default.
- W1997894511 abstract "Abstract The isoflavone phytoestrogens are still of current interest for their positive and negative health benefits. However, there are still many unanswered questions regarding their absorption, metabolism and bioavailability. Studies in this area require access to samples of both the isoflavone 7‐ O ‐glucosides, the form found in plants and the 7‐ O ‐glucuronides, which are important mammaliam metabolites. A new efficient, high‐yielding glycosylation procedure is described for isoflavones, which employs 2,2,2‐trifluoro‐ N ‐( p ‐methoxyphenyl)acetamidates as the glycosyl donors. This methodology was used to prepare the 7‐ O ‐glycosides of the three main isoflavones, daidzein, genistein and glycitein. The isoflavones were protected with hexanoyl groups which improved their solubility in organic solvents and improved the efficiency of the reaction. The same methodology was then adapted for the synthesis of the analogous 7‐ O ‐glucuronides. The new synthesis will provide access to large quantities of these compounds for further biological studies. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)" @default.
- W1997894511 created "2016-06-24" @default.
- W1997894511 creator A5044273464 @default.
- W1997894511 creator A5057550678 @default.
- W1997894511 date "2008-11-01" @default.
- W1997894511 modified "2023-09-23" @default.
- W1997894511 title "An Efficient Method for the Glycosylation of Isoflavones" @default.
- W1997894511 cites W1849840946 @default.
- W1997894511 cites W1857061086 @default.
- W1997894511 cites W1921169560 @default.
- W1997894511 cites W1954183840 @default.
- W1997894511 cites W1966343486 @default.
- W1997894511 cites W1970306797 @default.
- W1997894511 cites W1970428417 @default.
- W1997894511 cites W1988720181 @default.
- W1997894511 cites W1989273144 @default.
- W1997894511 cites W1994782334 @default.
- W1997894511 cites W2002095099 @default.
- W1997894511 cites W2009527950 @default.
- W1997894511 cites W2039201403 @default.
- W1997894511 cites W2048150346 @default.
- W1997894511 cites W2066301579 @default.
- W1997894511 cites W2068234763 @default.
- W1997894511 cites W2069607377 @default.
- W1997894511 cites W2077048665 @default.
- W1997894511 cites W2077967671 @default.
- W1997894511 cites W2081470634 @default.
- W1997894511 cites W2082786566 @default.
- W1997894511 cites W2083057801 @default.
- W1997894511 cites W2089363473 @default.
- W1997894511 cites W2091359397 @default.
- W1997894511 cites W2093700393 @default.
- W1997894511 cites W2101302352 @default.
- W1997894511 cites W2117120389 @default.
- W1997894511 cites W2142973990 @default.
- W1997894511 cites W2149934190 @default.
- W1997894511 cites W2160878876 @default.
- W1997894511 cites W2168845951 @default.
- W1997894511 cites W2952956812 @default.
- W1997894511 doi "https://doi.org/10.1002/ejoc.200800803" @default.
- W1997894511 hasPublicationYear "2008" @default.
- W1997894511 type Work @default.
- W1997894511 sameAs 1997894511 @default.
- W1997894511 citedByCount "22" @default.
- W1997894511 countsByYear W19978945112012 @default.
- W1997894511 countsByYear W19978945112013 @default.
- W1997894511 countsByYear W19978945112014 @default.
- W1997894511 countsByYear W19978945112015 @default.
- W1997894511 countsByYear W19978945112016 @default.
- W1997894511 countsByYear W19978945112017 @default.
- W1997894511 countsByYear W19978945112018 @default.
- W1997894511 countsByYear W19978945112019 @default.
- W1997894511 countsByYear W19978945112020 @default.
- W1997894511 countsByYear W19978945112022 @default.
- W1997894511 countsByYear W19978945112023 @default.
- W1997894511 crossrefType "journal-article" @default.
- W1997894511 hasAuthorship W1997894511A5044273464 @default.
- W1997894511 hasAuthorship W1997894511A5057550678 @default.
- W1997894511 hasConcept C126322002 @default.
- W1997894511 hasConcept C178790620 @default.
- W1997894511 hasConcept C181389837 @default.
- W1997894511 hasConcept C185592680 @default.
- W1997894511 hasConcept C194671627 @default.
- W1997894511 hasConcept C2777164284 @default.
- W1997894511 hasConcept C2777313579 @default.
- W1997894511 hasConcept C2778270713 @default.
- W1997894511 hasConcept C2778298627 @default.
- W1997894511 hasConcept C2779705811 @default.
- W1997894511 hasConcept C2780644575 @default.
- W1997894511 hasConcept C2780906977 @default.
- W1997894511 hasConcept C2780955279 @default.
- W1997894511 hasConcept C55493867 @default.
- W1997894511 hasConcept C71924100 @default.
- W1997894511 hasConcept C98274493 @default.
- W1997894511 hasConceptScore W1997894511C126322002 @default.
- W1997894511 hasConceptScore W1997894511C178790620 @default.
- W1997894511 hasConceptScore W1997894511C181389837 @default.
- W1997894511 hasConceptScore W1997894511C185592680 @default.
- W1997894511 hasConceptScore W1997894511C194671627 @default.
- W1997894511 hasConceptScore W1997894511C2777164284 @default.
- W1997894511 hasConceptScore W1997894511C2777313579 @default.
- W1997894511 hasConceptScore W1997894511C2778270713 @default.
- W1997894511 hasConceptScore W1997894511C2778298627 @default.
- W1997894511 hasConceptScore W1997894511C2779705811 @default.
- W1997894511 hasConceptScore W1997894511C2780644575 @default.
- W1997894511 hasConceptScore W1997894511C2780906977 @default.
- W1997894511 hasConceptScore W1997894511C2780955279 @default.
- W1997894511 hasConceptScore W1997894511C55493867 @default.
- W1997894511 hasConceptScore W1997894511C71924100 @default.
- W1997894511 hasConceptScore W1997894511C98274493 @default.
- W1997894511 hasIssue "33" @default.
- W1997894511 hasLocation W19978945111 @default.
- W1997894511 hasOpenAccess W1997894511 @default.
- W1997894511 hasPrimaryLocation W19978945111 @default.
- W1997894511 hasRelatedWork W1178620687 @default.
- W1997894511 hasRelatedWork W1966343486 @default.
- W1997894511 hasRelatedWork W2071346040 @default.
- W1997894511 hasRelatedWork W2080434876 @default.