Matches in SemOpenAlex for { <https://semopenalex.org/work/W1997904756> ?p ?o ?g. }
Showing items 1 to 92 of
92
with 100 items per page.
- W1997904756 endingPage "133" @default.
- W1997904756 startingPage "126" @default.
- W1997904756 abstract "The reduction of Fe(CN)5L2− (L = pyridine, isonicotinamide, 4,4′-bipyridine) complexes by ascorbic acid has been subjected to a detailed kinetic study in the range of pH 1–7.5. The rate law of the reaction is interpreted as a rate determining reaction between Fe(III) complexes and the ascorbic acid in the form of H2A(k0), HA−(k1), and A2− (k2), depending on the pH of the solution, followed by a rapid scavenge of the ascorbic acid radicals by Fe(III) complex. With given Ka1 and Ka2, the rate constants are k0 = 1.8, 7.0, and 4.4 M−1 s−1; k1 = 2.4 × 103, 5.8 × 103, and 5.3 × 103 M−1 s−1; k2 = 6.5 × 108, 8.8 × 108, and 7.9 × 108 M−1 s−1 for L = py, isn, and bpy, respectively, at μ = 0.10 M HClO4/LiClO4, T = 25°C. The kinetic results are compatible with the Marcus prediction. © 2005 Wiley Periodicals, Inc. Int J Chem Kinet 37: 126–133, 2005" @default.
- W1997904756 created "2016-06-24" @default.
- W1997904756 creator A5034537841 @default.
- W1997904756 creator A5043612943 @default.
- W1997904756 creator A5060985020 @default.
- W1997904756 date "2005-01-01" @default.
- W1997904756 modified "2023-10-14" @default.
- W1997904756 title "Kinetic studies of the reactions of pentacyanoferrate(III) complexes withL-ascorbic acid" @default.
- W1997904756 cites W1994990708 @default.
- W1997904756 cites W1996028583 @default.
- W1997904756 cites W2005429593 @default.
- W1997904756 cites W2006981409 @default.
- W1997904756 cites W2019227095 @default.
- W1997904756 cites W2020896615 @default.
- W1997904756 cites W2035579604 @default.
- W1997904756 cites W2036994186 @default.
- W1997904756 cites W2047722528 @default.
- W1997904756 cites W2050810798 @default.
- W1997904756 cites W2054869908 @default.
- W1997904756 cites W2054908221 @default.
- W1997904756 cites W2054929231 @default.
- W1997904756 cites W2078214666 @default.
- W1997904756 cites W2078737640 @default.
- W1997904756 cites W2080229355 @default.
- W1997904756 cites W2336002942 @default.
- W1997904756 cites W2990328806 @default.
- W1997904756 cites W3137739194 @default.
- W1997904756 cites W3139318693 @default.
- W1997904756 doi "https://doi.org/10.1002/kin.20052" @default.
- W1997904756 hasPublicationYear "2005" @default.
- W1997904756 type Work @default.
- W1997904756 sameAs 1997904756 @default.
- W1997904756 citedByCount "6" @default.
- W1997904756 countsByYear W19979047562014 @default.
- W1997904756 countsByYear W19979047562015 @default.
- W1997904756 crossrefType "journal-article" @default.
- W1997904756 hasAuthorship W1997904756A5034537841 @default.
- W1997904756 hasAuthorship W1997904756A5043612943 @default.
- W1997904756 hasAuthorship W1997904756A5060985020 @default.
- W1997904756 hasConcept C112887158 @default.
- W1997904756 hasConcept C121332964 @default.
- W1997904756 hasConcept C135889238 @default.
- W1997904756 hasConcept C139066938 @default.
- W1997904756 hasConcept C148898269 @default.
- W1997904756 hasConcept C155647269 @default.
- W1997904756 hasConcept C178790620 @default.
- W1997904756 hasConcept C179104552 @default.
- W1997904756 hasConcept C185592680 @default.
- W1997904756 hasConcept C2777246417 @default.
- W1997904756 hasConcept C2779485729 @default.
- W1997904756 hasConcept C2986274086 @default.
- W1997904756 hasConcept C31903555 @default.
- W1997904756 hasConcept C32909587 @default.
- W1997904756 hasConcept C62520636 @default.
- W1997904756 hasConcept C93391505 @default.
- W1997904756 hasConceptScore W1997904756C112887158 @default.
- W1997904756 hasConceptScore W1997904756C121332964 @default.
- W1997904756 hasConceptScore W1997904756C135889238 @default.
- W1997904756 hasConceptScore W1997904756C139066938 @default.
- W1997904756 hasConceptScore W1997904756C148898269 @default.
- W1997904756 hasConceptScore W1997904756C155647269 @default.
- W1997904756 hasConceptScore W1997904756C178790620 @default.
- W1997904756 hasConceptScore W1997904756C179104552 @default.
- W1997904756 hasConceptScore W1997904756C185592680 @default.
- W1997904756 hasConceptScore W1997904756C2777246417 @default.
- W1997904756 hasConceptScore W1997904756C2779485729 @default.
- W1997904756 hasConceptScore W1997904756C2986274086 @default.
- W1997904756 hasConceptScore W1997904756C31903555 @default.
- W1997904756 hasConceptScore W1997904756C32909587 @default.
- W1997904756 hasConceptScore W1997904756C62520636 @default.
- W1997904756 hasConceptScore W1997904756C93391505 @default.
- W1997904756 hasIssue "3" @default.
- W1997904756 hasLocation W19979047561 @default.
- W1997904756 hasOpenAccess W1997904756 @default.
- W1997904756 hasPrimaryLocation W19979047561 @default.
- W1997904756 hasRelatedWork W1964249238 @default.
- W1997904756 hasRelatedWork W1974638273 @default.
- W1997904756 hasRelatedWork W2014007590 @default.
- W1997904756 hasRelatedWork W2040425199 @default.
- W1997904756 hasRelatedWork W2066185644 @default.
- W1997904756 hasRelatedWork W2078411803 @default.
- W1997904756 hasRelatedWork W2078654761 @default.
- W1997904756 hasRelatedWork W2143083340 @default.
- W1997904756 hasRelatedWork W2474834692 @default.
- W1997904756 hasRelatedWork W319209893 @default.
- W1997904756 hasVolume "37" @default.
- W1997904756 isParatext "false" @default.
- W1997904756 isRetracted "false" @default.
- W1997904756 magId "1997904756" @default.
- W1997904756 workType "article" @default.