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- W1997912908 abstract "An exercise is presented in which the kinetics of the irreversible reaction of pennies in the heads-up state to pennies in the tails-up state is simulated by a hands-on, Monte Carlo approach. In addition, the exercise incorporates a second simulation in which the irreversible reaction of dice with a red face uppermost to a blue face uppermost is conducted. The transition states of the are assumed to be a penny that is in the process of being flipped or a die in the process of being rolled, respectively. Data collected by students who perform these simulations show that both reactions follow first-order decay kinetics. Arrhenius plots from these data yield activation energies comparable to assigned values and pre-exponential factors close to what would be expected based on the probability of a reactant achieving the correct orientation for conversion into product. A comparison of the values obtained for the pre-exponential factors for the different simulations allows students to semi-qu..." @default.
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- W1997912908 date "2007-11-01" @default.
- W1997912908 modified "2023-10-18" @default.
- W1997912908 title "Visualizing the Transition State: A Hands-on Approach to the Arrhenius Equation" @default.
- W1997912908 doi "https://doi.org/10.1021/ed084p1776" @default.
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