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- W1997966802 abstract "Generalized oscillator strengths, oscillator strengths, and total cross sections are calculated within the first Born approximation for 1σg→nσu and nπu transitions in H2; for selected 2σu, 1πu, and 3σg to nπg, nπu, nσg, nσu, and nδg transitions in N2; and for the 1πg→nπu excitations in O2 in addition to transitions equivalent to those studied in N2. When compared with the corresponding experimental spin-allowed excitations good agreement is obtained in most cases. The spheroidal potential approximation within the independent particle model (IPM) is analyzed as the source of the problem for several of the transitions in N2 and O2 which yield properties smaller than the experimental results by 2 orders of magnitude. The theoretical result, previously unreported, for the 1πu→1δg transition in N2 suggests that its intensity should be compared to the 1πu→1πg(b′←X) and that it corresponds to the e←X transition. The theoretical result for the 1πu→1δg transition in O2 for which there is no experimental data is also reported." @default.
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- W1997966802 date "1977-05-01" @default.
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- W1997966802 title "Generalized oscillator strengths and total cross sections for H2, N2, and O2 with an independent particle model" @default.
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- W1997966802 doi "https://doi.org/10.1063/1.434443" @default.
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