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• W1998014468 abstract "A thermodynamic assessment of lead-doped Bi-2223 with emphasis on compositions and oxygen partial pressures within the homogeneity region prior to solid-state decomposition is presented. Equations for the variation of oxygen partial pressure with composition and temperature have been derived from our EMF measurements. Long-term metastability was indicated during cycling over a temperature range of ∼ 700–815°C of a lead-doped Bi-2223 sample having an oxygen-deficient stoichiometry of 9.64 prior to solid-state decomposition corresponding to the diphasic CuOCu2O system. A trend of increasing negative values of the partial molar enthalpy ΔH(O2) and entropy ΔS(O2 with increasing oxygen deficiency of the condensed phase indicated an increase in ordering of the cuprate structure prior to solid-state decomposition." @default.
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• W1998014468 date "1996-04-01" @default.
• W1998014468 modified "2023-09-29" @default.
• W1998014468 title "Some aspects of the thermodynamic behaviour of the lead-doped Bi-2223 system" @default.
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• W1998014468 doi "https://doi.org/10.1016/0921-4534(96)00132-3" @default.
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