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• W1998024960 abstract "The synthesis, the optical and magnetic properties and the electronic structure of the rare-earth oxytellurides of formula Ln2O2Te (Ln = La, Sm and Gd) are reported. The magnetic measurements show that La2O2Te exhibit a diamagnetic behavior. The value of the magnetization M of Gd2TeO2 at our highest available field (50 kOe) is about 5.5μB, well below the expected value for two independent Gd ions (2gJ = 14μB) confirming the antiferromagnetic character of this compound. The magnetic properties of Sm2TeO2 reveal that Sm is in its 3+ oxidation state with a large Van Vleck contribution. The electronic structure calculations, studied by means of a first principles DFT approach, are consistent with the optical measurements and suggest an indirect band gap semiconductor behavior." @default.
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• W1998024960 date "2008-02-01" @default.
• W1998024960 modified "2023-09-30" @default.
• W1998024960 title "Optical, magnetic and electronic properties of Ln2O2Te (Ln=La, Sm and Gd)" @default.
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• W1998024960 doi "https://doi.org/10.1016/j.materresbull.2007.03.008" @default.
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