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- W1998030488 abstract "The rates and products of addition of 4-chlorobenzenesulfenyl chloride to E- and Z-3-methyl-2-pentene, E- and Z-3,4-dimethyl-2-pentene, E- and Z-3,4,4-trimethyl-2-pentene, and 2,4,4-trimethyl-2-pentene were studied to determine if the mechanism involved a tertiary β arylthio carbocation. It was found that the rates of addition are not as fast as one would predict based on the polar effects of the substituents on the rate of addition to mono- and disubstituted alkenes. The products are formed by anti-stereospecific addition as in the case of addition to 1,2-disubstituted alkenes. As a result it is concluded that the reaction occurs by means of the usual mechanism involving a bridged thiiranium ion." @default.
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- W1998030488 date "1987-06-01" @default.
- W1998030488 modified "2023-09-26" @default.
- W1998030488 title "The rates and products of addition of 4-chlorobenzenesulfenyl chloride to a series of trisubstituted alkenes" @default.
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- W1998030488 doi "https://doi.org/10.1139/v87-196" @default.
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