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- W1998052015 abstract "The aluminium-rich compounds GdAl4 and TbAl4 precipitate in aluminium-gadolinium and aluminium-terbium alloys cast from the liquid and decompose by a peritectoid reaction at 400° and 420°C, respectively, to form α-aluminium plus GdAl3 and TbAl3. The latter compounds form eutectic mixtures with Al at approximately 10 wt.% Gd and Tb with melting points of 643° and 644°C, respectively. Thermal analysis and X-ray diffraction experiments indicate that a solid-state transformation possibly involving a rearrangement or clustering of vacancies is initiated on cooling GdAl3 to 641°C and TbAl3 to 642°C. GdAl4 and TbAl4 are isostructural with orthorhombic UAl4. Both GdAl3 and TbAl3 have structures based on an assembly of close-packed layers containing a ratio of one lanthanide to three aluminium atoms in each layer. The stacking sequences of the layers are ABA… for GdAl3 (SnNi3 structure) and ABABCBCACA … for TbAl3 (rhombohe dral PuAl3 structure)." @default.
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- W1998052015 date "1967-10-01" @default.
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- W1998052015 title "Phase equilibria in aluminium-rich alloys of aluminium-gadolinium and aluminium-terbium" @default.
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- W1998052015 doi "https://doi.org/10.1016/0022-5088(67)90036-7" @default.
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