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- W1998082146 abstract "Polyvinylidene fluoride (PVDF) films, filled with mass fractions w≤15% of CoCl2, were prepared. The X-ray diffraction (XRD) scans evidenced semicrystalline structures containing α- and/or β-PVDF phases. IR spectra confirmed these findings, and revealed some structural defects such as mono- and di-fluorinated alkenes and head-to-head segments. The optical absorption spectra suggested the presence of: (a) two optical gaps (one of them, Eg2, depends on W); (b) tetrahedral Co(II) coordination for all of the filling levels (FL); and (c) octahedral Co(II) forms at 15% FL. The electrical resistivity results are discussed on the basis of the modified interpolaron hopping model of Kuivalainen et al., Phys Rev 1985;B31:7900. The temperature and FL dependences of the calculated hopping distance (Ro) are discussed. It is implied that the difluorinated alkenes exert a significant influence on Eg2 and Ro. The electron spin resonance (ESR) spectra confirmed the optical absorption implications." @default.
- W1998082146 created "2016-06-24" @default.
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- W1998082146 date "2000-09-01" @default.
- W1998082146 modified "2023-09-27" @default.
- W1998082146 title "Structural, electrical and electron spin resonance properties of CoCl2-filled polyvinylidene fluoride films" @default.
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- W1998082146 doi "https://doi.org/10.1016/s0142-9418(99)00057-4" @default.
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