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- W1998085352 abstract "Abstract The compounds [Ru 3 (μ-H)(μ 3 -ampy)(CO) 9 ] ( 1 ) and [Ru 3 (μ-H) 2 (μ 3 -ampy)(CO) 9 ]BF 4 ( 2 ) (Hampy = 2-amino-6-meth (dppm) to give [Ru 3 (μ-H)(μ 3 -ampy)(CO) 7 (dppm)] ( 3 ) and [Ru 3 (η-H) 2 (μ 3 -ampy)(CO) 7 (dppm)]BF 4 ( 4 ), respectiv ligand are cis to both the hydride and the amido-fragment of the bridging ampy ligand, whereas in complex 4 each P atom is trans to a hydri 2 affords [Ru 3 (μ-H) 2 (μ 3 -ampy)(CO) 7 (dppm)BF 4 ( 5 ), which is an isomer of complex 4 ; in fact, 5 can also be obtain tetrahydrofuran. Complex 5 undergoes deprotonation upon reaction with potassium methoxide or triethylamine, giving 3 ; however, the reaction of methoxycarbonyl derivative [Ru 3 (μ-H) 2 (μ 3 amfy)(CO 2 Me)(CO) 6 (dppm)] ( 6 ), which contains the CO 2 Me group in an equatorial" @default.
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- W1998085352 date "1992-04-01" @default.
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- W1998085352 title "Synthesis and reactivity of triruthenium carbonyl clusters containing bis(diphenylphosphino)methane and the face-bridging ligand 2-amido-6-methylpyridi" @default.
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- W1998085352 doi "https://doi.org/10.1016/0022-328x(92)80074-8" @default.
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