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• W1998096178 abstract "The results of several kinetic studies of the oxidative addition of aryl halides (ArX) to several PdL2 catalysts have been analyzed to obtain quantitative information on the values of the kinetic parameters. The latter are found to be consistent with reactivity patterns observed for analogous reactions of other Pd(0) systems. These results are applied to several types of kinetic studies of the amination of aryl halides with Pd(0) catalysts. The analysis uses numerical integration of the rate equations after appropriate steady-state assumptions. It is found that in two cases the reaction rate under catalytic conditions is reasonably consistent with rate-limiting oxidative addition. However, in two cases the catalytic rate is either faster or slower than predicted if oxidative addition is rate-limiting. In addition, one example shows a kinetic influence of complexation of Pd(II) by the amine, while for another reductive elimination of the product is rate-limiting." @default.
• W1998096178 created "2016-06-24" @default.
• W1998096178 creator A5089444540 @default.
• W1998096178 date "2007-08-08" @default.
• W1998096178 modified "2023-09-24" @default.
• W1998096178 title "Amination of Aryl Halides: Quantitative Assessment of Stoichiometric and Catalytic Kinetic Studies" @default.
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• W1998096178 doi "https://doi.org/10.1021/om7003223" @default.
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