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• W1998096575 abstract "We report herein the X-ray magnetic circular dichroism (XMCD) at the Au L2,3 edges of a series of Au clusters protected by glutathione (GSH). The samples used here included AuN(SG)M with (N, M) = (10, 10), (15, 13), (18, 14), (22, 16), (25, 18), (29, 20), (39, 24) and a sodium gold(I) thiomalate (SGT) as a reference. Magnetic moments per cluster were found to be increased with size, whereas those per Au−S bond were nearly constant. This finding suggests that a localized hole created by Au−S bonding at the gold/glutathione interface, rather than the quantum size effect, is responsible for the spin polarization of gold clusters." @default.
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• W1998096575 date "2006-08-25" @default.
• W1998096575 modified "2023-10-16" @default.
• W1998096575 title "X-ray Magnetic Circular Dichroism of Size-Selected, Thiolated Gold Clusters" @default.
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• W1998096575 doi "https://doi.org/10.1021/ja062815z" @default.
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