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- W1998097879 abstract "Five Cd(II) complexes, {[Cd4(MTZ)2(H2O)2Cl8]·0.5H2O}n (1), [Cd(MTZ)2Br2] (2), [Cd2(MTZ)2I4] (3), [Cd2(MTZ)2(H2O)8] (SO4)2 (4), {[Cd(MTZ)2(H2O)2](ClO4)2}n (5), based on different anions with the mercaptotetrazole ligand MTZ (MTZ = 1-(2-dimethylamino-ethyl)-5-mercapto-1H-tetrazole) have been synthesized. Employment of different anions can result in structural diversity in 1–5. In 1, the Cd(II) ions make use of μ2-Cl, μ3-Cl bridging each other to form a novel Cd4Cl8 inorganic network structure. On the other hand, the 2D structure is further stabilized by MTZ as a tridentate bridging organic ligand holding three adjacent Cd(II) ions. In 2, MTZ as a terminal ligand coordinates with a Cd(II) ion to form a mononuclear structure. As a μ2, η2 bridging ligand, MTZ links Cd(II) ions to form a dimeric structures in 3 and 4, and a 1D infinite chain in 5. In addition, the luminescent properties of 1–5 have been investigated in the solid state at room temperature." @default.
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- W1998097879 date "2011-08-01" @default.
- W1998097879 modified "2023-09-24" @default.
- W1998097879 title "Anion-mediated self-assembly: Five Cd(ІІ) coordination aggregates with a mercaptotetrazole ligand" @default.
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- W1998097879 doi "https://doi.org/10.1016/j.poly.2011.05.038" @default.
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