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- W1998106867 abstract "A series of new three-dimensional (3D) lanthanide–transition metal (4f–3d) heterobimetallic open frameworks, [Ln2(1,2-bdc)2(H2O)2 Cu(inic)2](ClO4) (Ln=Eu (1), Tb (2), Nd (3) and Sm (4); 1,2-bdc=1,2-benzenedicarboxylate; Hinic=isonicotinic acid) have been hydrothermally synthesized and characterized by elemental analysis, IR, TG and single-crystal X-ray diffraction analysis. Compounds 1–4 are isostructural. They possess a new anion-templated 3D heterobimetallic open framework, which is observed for the first time in the {Ln/TM/bdc/inic} (TM=transition metal) system. Compounds 1 and 2 exhibit the characteristic fluorescent properties of Eu(III) and Tb(III), respectively." @default.
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- W1998106867 date "2008-06-01" @default.
- W1998106867 modified "2023-10-14" @default.
- W1998106867 title "New anion-templated 3D heterobimetallic open frameworks based on lanthanide-carboxylate layers and copper pillars" @default.
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- W1998106867 doi "https://doi.org/10.1016/j.jssc.2008.03.027" @default.
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