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- W1998120401 abstract "A pulsed supersonic CO laser has been sued to produce a time-dependent CO vibrational distribution which is strongly vibration-vibration pumped. The time evolution of the populations of individual vibrational states of the X 1Σ+ and the A1Π manifolds was observed through X state infrared emission and A–X ultraviolet emission. The X state first-overtone IR signals were observed from ν = 2 through ν = 40. The time-dependence of ν = 11, 17, 24, 29 and 35 was analyzed in detail. A–X (fourth positive) emission signals originating from ν = 1 to ν = 8 were observed and analyzed. In addition, the timing of the formation of C2 was observed from the Δν = −1 sequence in the blue Swan-band emission. Kinetic modeling calculations have been performed which show good agreement with the measured experimental rise times. Near-resonance vibration-vibration transfer rates among CO(X 1Σ+, ν) states to ν = 40 have been inferred at a gas temperature of 370 K. These calculations also reproduce the observed X state vibrational distribution and the low-ν relaxation data in the literature. An estimate of the internal X-A collisionally induced vibration-electronic coupling has also been obtained." @default.
- W1998120401 created "2016-06-24" @default.
- W1998120401 creator A5010580969 @default.
- W1998120401 creator A5024430907 @default.
- W1998120401 date "1986-09-01" @default.
- W1998120401 modified "2023-10-14" @default.
- W1998120401 title "Vibrational energy exchange rates in carbon monoxide" @default.
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- W1998120401 doi "https://doi.org/10.1016/0301-0104(86)85008-x" @default.
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