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- W1998156744 abstract "The multiphase heterogeneous enantioselective hydrogenation of acetophenone in the presence of cinchona-modified Pt/C was investigated. The system demonstrated the feasibility of this reaction on non-activated ketones. The reaction proceeded selectively, at room temperature and atmospheric pressure, towards the formation of 1-phenylethanol, with up to 20% ee (enantiomeric excess) of either enantiomer depending on the modifier used. A mode of action of the modifier is proposed to account for the mechanism. A comparison with other systems indicates that the investigated system likely acts by a different mechanism, and that it is quite specific for acetophenone." @default.
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- W1998156744 date "2002-03-01" @default.
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- W1998156744 title "Multiphase heterogeneous catalytic enantioselective hydrogenation of acetophenone over cinchona-modified Pt/C" @default.
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- W1998156744 doi "https://doi.org/10.1016/s1381-1169(01)00423-x" @default.
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