FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1998166721> ?p ?o ?g. }

• W1998166721 endingPage "1008" @default.
• W1998166721 startingPage "999" @default.
• W1998166721 abstract "The ruthenium(II) complexes [Ru(CHCHR){κ2-S2P(OEt)2}(CO)(PPh3)2] (R = But, C6H4Me-4) are formed on reaction of (NH4)[S2P(OEt)2] with [Ru(CHCHR)Cl(CO)(BTD)(PPh3)2] (BTD = 2,1,3-benzothiadiazole), while the enynyl complex [Ru(C(CCPh)CHPh)Cl(CO)(PPh3)2] loses a phosphine on treatment with the same ligand to yield [Ru(η3-PhCC–CCHPh){κ2-S2P(OEt)2}(CO)(PPh3)]. The stilbenyl complexes [Ru(CPhCHPh)Cl(CA)(PPh3)2] (A = O, S) react with (NH4)[S2P(OEt)2] to provide the dimers [Ru(CPhCHPh){μ–κ1–κ2–S2P(OEt)2}(CA)(PPh3)]2. Treatment of the thiocarbonyl complex with carbon monoxide results in migratory insertion of the vinyl and CS ligands to provide [Ru(η2-SCCPhCHPh){κ2-S2P(OEt)2}(CO)(PPh3)]. On treatment with excess 4-ethynyltoluene, the known compound [RuH{κ2-S2P(OEt)2}(CO)(PPh3)2] undergoes insertion of the alkyne to provide an alternative route to [Ru(CHCHC6H4Me-4){κ2-S2P(OEt)2}(CO)(PPh3)2]. The compounds [Ru(CHCHR){κ2-S2P(OEt)2}(CO)(PPh3)2] (R = n-C4H9, CH2OSi(But)Me2, CO2Me, Fc, CPh2OH, (HO)C6H10) were prepared cleanly by this route using HCCR. On stirring [RuH{κ2-S2P(OEt)2}(CO)(PPh3)2] over a longer period of time with excess 4-ethynyltoluene, the acetylide [Ru(CCC6H4Me–4){κ2-S2P(OEt)2}(CO)(PPh3)2] is generated. Heating [Ru(CHCHC6H4Me-4){κ2-S2P(OEt)2}(CO)(PPh3)2] with excess 3,3-dimethylbut-1-yne in 1,2-dichloroethane led to elimination of the vinyl ligand and formation of the acetylide compound [Ru(CCBut){κ2-S2P(OEt)2}(CO)(PPh3)2]. A small amount of the side product, [RuCl{κ2-S2P(OEt)2}(CO)(PPh3)2], was also formed. This could be obtained directly from the reaction of [RuH{κ2-S2P(OEt)2}(CO)(PPh3)2] with N-chlorosuccinimide. The related mixed-donor ligand, K[OP(S)(OEt)2], reacts with [Ru(CHCHC6H4Me-4)Cl(CO)(BTD)(PPh3)2] to yield [Ru(CHCHC6H4Me-4){κ2-OP(S)(OEt)2}(CO)(PPh3)2]. The molecular structure of [Ru(CHCHCPh2OH){κ2-S2P(OEt)2}(CO)(PPh3)2] was determined crystallographically." @default.
• W1998166721 created "2016-06-24" @default.
• W1998166721 creator A5062312496 @default.
• W1998166721 creator A5062396497 @default.
• W1998166721 creator A5067212029 @default.
• W1998166721 creator A5087959120 @default.
• W1998166721 date "2012-01-01" @default.
• W1998166721 modified "2023-09-27" @default.
• W1998166721 title "Synthesis and reactivity of dialkyldithiophosphate complexes of ruthenium(<scp>ii</scp>)" @default.
• W1998166721 cites W1027796177 @default.
• W1998166721 cites W1491133765 @default.
• W1998166721 cites W1532095700 @default.
• W1998166721 cites W1564535687 @default.
• W1998166721 cites W169209735 @default.
• W1998166721 cites W1703690708 @default.
• W1998166721 cites W1934351344 @default.
• W1998166721 cites W1964306044 @default.
• W1998166721 cites W1965306872 @default.
• W1998166721 cites W1968153481 @default.
• W1998166721 cites W1968746703 @default.
• W1998166721 cites W1971016000 @default.
• W1998166721 cites W1971323888 @default.
• W1998166721 cites W1976014355 @default.
• W1998166721 cites W1979568951 @default.
• W1998166721 cites W1979914650 @default.
• W1998166721 cites W1980354701 @default.
• W1998166721 cites W1980548379 @default.
• W1998166721 cites W1982695875 @default.
• W1998166721 cites W1985466371 @default.
• W1998166721 cites W1988638442 @default.
• W1998166721 cites W1988854647 @default.
• W1998166721 cites W1988917889 @default.
• W1998166721 cites W1994413807 @default.
• W1998166721 cites W1997291246 @default.
• W1998166721 cites W1999123688 @default.
• W1998166721 cites W1999178564 @default.
• W1998166721 cites W2000920945 @default.
• W1998166721 cites W2002412700 @default.
• W1998166721 cites W2003886722 @default.
• W1998166721 cites W2004562733 @default.
• W1998166721 cites W2005013481 @default.
• W1998166721 cites W2005775469 @default.
• W1998166721 cites W2006569869 @default.
• W1998166721 cites W2007980418 @default.
• W1998166721 cites W2011278098 @default.
• W1998166721 cites W2012768980 @default.
• W1998166721 cites W2013232915 @default.
• W1998166721 cites W2013623659 @default.
• W1998166721 cites W2015537290 @default.
• W1998166721 cites W2016648396 @default.
• W1998166721 cites W2018300236 @default.
• W1998166721 cites W2018928731 @default.
• W1998166721 cites W2020676207 @default.
• W1998166721 cites W2022056562 @default.
• W1998166721 cites W2023177859 @default.
• W1998166721 cites W2026511009 @default.
• W1998166721 cites W2026617028 @default.
• W1998166721 cites W2028787213 @default.
• W1998166721 cites W2031378542 @default.
• W1998166721 cites W2035824297 @default.
• W1998166721 cites W2036397965 @default.
• W1998166721 cites W2036539671 @default.
• W1998166721 cites W2041851365 @default.
• W1998166721 cites W2043163362 @default.
• W1998166721 cites W2046568860 @default.
• W1998166721 cites W2047164719 @default.
• W1998166721 cites W2047616297 @default.
• W1998166721 cites W2049196908 @default.
• W1998166721 cites W2051832424 @default.
• W1998166721 cites W20525805 @default.
• W1998166721 cites W2054066503 @default.
• W1998166721 cites W2054420459 @default.
• W1998166721 cites W2054853198 @default.
• W1998166721 cites W2055088799 @default.
• W1998166721 cites W2057585656 @default.
• W1998166721 cites W2060923461 @default.
• W1998166721 cites W2062704149 @default.
• W1998166721 cites W2064153195 @default.
• W1998166721 cites W2064991276 @default.
• W1998166721 cites W2065531464 @default.
• W1998166721 cites W2066066285 @default.
• W1998166721 cites W2066670079 @default.
• W1998166721 cites W2068230998 @default.
• W1998166721 cites W2072101689 @default.
• W1998166721 cites W2072576123 @default.
• W1998166721 cites W2073587409 @default.
• W1998166721 cites W2076095314 @default.
• W1998166721 cites W2078943947 @default.
• W1998166721 cites W2081685220 @default.
• W1998166721 cites W2082597153 @default.
• W1998166721 cites W2084741339 @default.
• W1998166721 cites W2085456538 @default.
• W1998166721 cites W2089328357 @default.
• W1998166721 cites W2091798791 @default.
• W1998166721 cites W2091838702 @default.
• W1998166721 cites W2094023252 @default.
• W1998166721 cites W2100926494 @default.
• W1998166721 cites W2101469636 @default.

• next