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- W1998185127 abstract "Titanium polyamines of the form below were synthesized using aqueous solution and interfacial routes. The products are insoluble in all tested solvents. Some of the products exhibit RNH3+ endgroups and/or internal protonated amines. Products from aromatic diamines possess endgroups derived from the reaction of RCp2TiCl with Et3N when Et3N is used as the added base. On a effectué la synthèse des polyamines titanées de la forme ci-dessous en utilisant des solutions aqueuses et des voies d'accès interfaciales. Les produits sont insolubles dans tous les solvants qui ont été essayés. Certains produits ont des groupements RNH3+ en bout de chaine et/ou des amines protonées internes. Les produits obtenus à partir des diamines aromatiques ont des groupements en bout de chaîne provenant de la réaction de RCp2 TiCl avec Et3 N quand on utilise Et3N comme base ajoutée. Per mezzo di soluzione acquosa e sfruttando percorsi interfacciali, si sono sintetizzati delle poliammine di titanio di formula sottoriportata. I prodotti ricavati sono insolubili in tutti i solventi provati. Alcuni di essi presentano gruppi terminali RNH3+ e/oppure ammine interne protonate. I prodotti ricavati da diammine aromatiche posseggono gruppi terminali che si formano in seguito alla reazione di RCp2TiCl con Et3N con quest'ultima impiegata come base aggiunta. Titan-haltige Polyamine von der unten angegebenen Art wurden nach der Grenzflächen Methode durch Verwendung einer wässrigen Lösung synthetisiert. Die Produkte sind in allen untersuchten Lösungsmitteln unlöslich. Einige der Produkte enthalten RNH3+ Endgruppen und/oder protonierte Amine im Innern. Produkte aus aromatischen Diaminen besitzen Endgruppen, die sich von der Reaktion von RCp2TiCl mit Et3N ableiten, wenn Et3N als Base zugesetzt wird." @default.
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- W1998185127 date "1972-12-01" @default.
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- W1998185127 title "Synthesis of titanium polyamines via the interfacial and aqueous solution techniques" @default.
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- W1998185127 doi "https://doi.org/10.1016/0014-3057(72)90021-3" @default.
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