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- W1998194080 abstract "In order to develop a full understanding for the toxic nature of aluminum (AI), it is important to first discuss the chemistry of this metal. Aluminum has a primary hydration number of 6, remains unhydrolyzed below pH 3, exhibits only a trivalent state (AI(III», and has an ionic radius of 0.51 }...I Aluminum may become extensively hydrolyzed at elevated pH, but this state is metastable with respect to the formation of Al(OHh The content of hydrated Al species in the solution is determined by Al concentration, pH, and conditions of the hydrolysis reaction. z Although Al exists only in the trivalent state (AI(III», its inner hydration shell is hexacoordinated, with a LlHHYD = 1141 Kcallmol. This high energy results from the electrostatic interaction of ions and water dipole3 causing soluble Al species to retain some of these water molecules during interactions with biologic ligands. Aluminum is soluble in aqueous solutions only under constrained conditions governed by pH and metal ion concentration (Table 1). Solvation of Al proceeds according to the following general reaction:" @default.
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- W1998194080 date "1985-11-01" @default.
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- W1998194080 title "Aluminum Interaction With Biomolecules: The Molecular Basis for Aluminum Toxicity" @default.
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- W1998194080 doi "https://doi.org/10.1016/s0272-6386(85)80093-7" @default.
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