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- W1998199479 abstract "Intermediate product of the reaction of MoOS2(S2CNR2)2 and PPh3 in dichloroethane has been detected by ESR spectroscopy. Two ESR signals have been observed at low temperature in the reaction system which was stopped by quenching it in liquid nitrogen. The g values are 2.020 ± 0.001 and 1.972 ± 0.001 respectively. The signal at g = 2.020 is attributed to a reaction intermediate with pentavalent molybdenum. A reaction mechanism has been proposed which is consistent with the observation of pentavalent molybdenum as the intermediate in the process of reaction." @default.
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- W1998199479 date "1989-09-01" @default.
- W1998199479 modified "2023-10-15" @default.
- W1998199479 title "Study of the reaction of MoOS2(S2CNR2)2 with PPh3 in 1,2-dichloroethane: Part II. Detection of reaction intermediate pentavalent molybdenum using ESR method at low temperature" @default.
- W1998199479 cites W1034335324 @default.
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- W1998199479 doi "https://doi.org/10.1002/kin.550210903" @default.
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