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- W1998199610 abstract "We present scanning tunnelling microscopy studies and first principles calculation on the 2D crystallization of pentagonal pentamethylcorannulene on a Cu(111) surface under ultrahigh vacuum in the temperature range of 50 K to 400 K. The observed 2D crystal phases and their packing densities are compared to tiling options of hard pentagons. Temperature change-induced reversible phase transitions reveal entropic effects in 2D crystallization. Only inclusion of dispersion interactions into density functional theory yields structures observed experimentally at low temperatures." @default.
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- W1998199610 date "2012-01-01" @default.
- W1998199610 modified "2023-09-23" @default.
- W1998199610 title "Pentagonal tiling with buckybowls: pentamethylcorannulene on Cu(111)" @default.
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- W1998199610 doi "https://doi.org/10.1039/c2cp41732d" @default.
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