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- W1998256325 abstract "Abstract The 1,2-migration of an ethylthio group with inversion of configuration at the C-1 and C-2 atoms was observed during the attempted preparation of 2,3-orthoester derivatives of ethyl 1-thio-α- l -rhamnopyranoside. The rearrangement leading to the formation of methyl 2-thio-β- l -glucopyranosides could be avoided by preparing the orthoester in DMF rather than in acetonitrile and by using a controlled amount of acid catalyst." @default.
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- W1998256325 date "1991-06-01" @default.
- W1998256325 modified "2023-09-26" @default.
- W1998256325 title "Incidence and avoidance of stereospecific 1,2-ethylthio group migration during the synthesis of ethyl 1-thio-α-l-rhamnopyranoside 2,3-orthoester" @default.
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- W1998256325 doi "https://doi.org/10.1016/0008-6215(91)84041-c" @default.
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