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- W1998271476 abstract "The application of some newly prepared aryl 4,6-O-(R)-benzylidene-2,3-bis(O-diphenylphosphino)-β-d-glucopyranosides 4b–g in form of their rhodium(I) chelates as catalysts in asymmetric hydrogenation of dehydroamino acid derivatives shows similar high enantioselectivities to the parent ligand Ph-β-glup 4a whose chelate has found industrial application for production of l-dopa. The importance of all-equatorial arrangement of the pyranoside substituents for enantioselectivities of more than 90% ee is demonstrated by comparison with analogous structures carrying axial groups and a rule could be set up. A spectroscopic investigation of some important representatives is added." @default.
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- W1998271476 date "1993-10-01" @default.
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- W1998271476 title "Carbohydrate phosphinites as chiral ligands for asymmetric syntheses catalyzed by complexes. Part X. Importance of all-equatorial arrangement in vicinal bisphosphinite hexapyranoside ligands for rhodium catalyzed asymmetric hydrogenation" @default.
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- W1998271476 doi "https://doi.org/10.1016/0304-5102(93)85056-y" @default.
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