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- W1998284987 abstract "The alkylidynetrinickel clusters (NiCp)3C(CH2)8CH31, (NiCp)3CCH32 and tetrakis(η5-cyclopentadienyl)dihydridotetranickel (NiCp)4H23 were isolated from the reaction mixture of nickelocene with phenyllithium in the presence of 1-decene. (NiCp)3C(CH2)4CH3 and the clusters 2 and 3 were obtained in reaction with 1-hexene. In the presence of 2,4,4-trimethyl-1-pentene, cluster 3 was obtained as the main product of the reaction. In the reaction with 1-decene, organic products (olefins, biphenyl, o-terphenyl, quartephenyl) were identified by GC/MS analyses. The structure of 3 has been determined by X-ray diffraction and characterized by 1H and 13C NMR, MS and IR. On the basis of organonickel and organic products formed, the mechanism of the sp2-hybridized C-H bond activation by cyclopentadienylnickel species has been discussed." @default.
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- W1998284987 date "1997-05-01" @default.
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- W1998284987 title "The activation of C-H bonds in terminal olefins by cyclopentadienylnickel species" @default.
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- W1998284987 doi "https://doi.org/10.1016/s0022-328x(96)06777-0" @default.
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