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- W1998285365 abstract "The perturbation solution of the Percus–Yevick equation, based on the known solution for hard-sphere interactions, is found for the square-mound potential. The correlation functions are expanded in powers of the parameter α, related to the height of the mound, i.e., describing the deviation of the interactions from the hard-sphere ones. An algorithm for the calculation of subsequent coefficients is given. Numerical calculations show, however, that the series converges slowly and thus a few terms approximate the whole series with sufficient accuracy for small (but still finite) values of α, i.e., for almost hard-sphere interactions, only. For mounds high enough the system behaves very similarly to the hard-sphere system, but it quickly loses its ’’hard’’ characteristics as the mound decreases. This result, in the light of the success of the recent perturbation theory of liquids, seems to suggest that, whereas fairly significant changes of the potential in the outside of the hard core may be treated as small perturbations, even a small change inside the hard core very strongly perturbs the properties of the system." @default.
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- W1998285365 date "1977-11-01" @default.
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- W1998285365 title "Perturbation solution of the Percus–Yevick equation for the square‐mound potential" @default.
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- W1998285365 doi "https://doi.org/10.1063/1.523193" @default.
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