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- W1998309968 abstract "A series of cationic half-sandwich arene ruthenium(II) complexes of general formula [Ru(η6-p-cymene)Cl(L)]Cl have been synthesized from the reaction of [Ru(η6-p-cymene)Cl2]2 with thiosemicarbazone derivatives (L). Characterization of the complexes were accomplished by analytical and spectral (FT-IR, UV–Vis, 1H NMR) methods. Single crystal structure determination reveals the presence of a pseudooctahedral three-legged piano stool conformation. All the complexes exhibit a quasi-reversible one electron reduction in the range from −0.75 to −0.85 V. Further, the catalytic activity of the titled complex has been investigated in the transfer hydrogenation of ketones in the presence of isopropanol/NaOH." @default.
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- W1998309968 date "2010-11-01" @default.
- W1998309968 modified "2023-10-08" @default.
- W1998309968 title "Arene ruthenium(II) p-chloroacetophenone phenylthiosemicarbazone complex mediated transfer hydrogenation of ketones" @default.
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- W1998309968 doi "https://doi.org/10.1016/j.inoche.2010.07.026" @default.
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