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• W1998397652 abstract "Abstract The effects of stoichiometry on microstructural evolution during ordering of Ni 3 V compound that transforms from cubic disorder phase (A1(fcc)) to tetragonal order phase (D0 22 ) were investigated by scanning electron microscopy, X-ray diffraction and Vickers hardness measurement. In as-homogenized state, either Ni 75 V 25 , Ni 74 V 26 or Ni 76 V 24 alloys exhibited lamellar-like microstructure composed of three sets of D0 22 variant structures with an orthogonal orientation relation to each other, and therefore the disorder phase stable at high temperature was not retained at low temperature. Recrystallized new grains nucleated preferentially at grain boundaries and then eliminated the lamellar-like microstructure as annealing time or annealing temperature increases, like ordinary recrystallization process. The microstructural evolution from the lamellar-like microstructure to the recrystallized grains was the fastest in the Ni 74 V 26 alloy, followed by the Ni 75 V 25 alloy and was the slowest in the Ni 76 V 24 alloy. Hardness of the lamellar-like microstructure was higher than that of the recrystallized grains. Boron doping retarded the microstructural evolution in the Ni 75 V 25 alloy. The microstructural evolution was correlated with anisotropic parameter between two lattice constants, a and c , and was shown to be more significant as this parameter is larger. The results were discussed in terms of the effects of stoichiometry and boron doping on driving force and atomic diffusion by which the microstructural evolution is affected." @default.
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• W1998397652 date "2013-12-01" @default.
• W1998397652 modified "2023-09-27" @default.
• W1998397652 title "The effect of stoichiometry on the microstructural evolution during ordering of Ni3V" @default.
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• W1998397652 doi "https://doi.org/10.1016/j.msea.2013.09.037" @default.
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