Matches in SemOpenAlex for { <https://semopenalex.org/work/W1998399592> ?p ?o ?g. }
- W1998399592 endingPage "3305" @default.
- W1998399592 startingPage "3297" @default.
- W1998399592 abstract "The RuIII bis(anilide) dimer [Cp*RuCl(μ-NHPh)]2 (1a) is formed upon reaction of (Cp*RuCl)4 with 1,2-diphenylhydrazine in benzene. An X-ray crystal structure shows a centrosymmetric (Ci) dimer with a planar Ru2N2 core. Reaction of (Cp*RuCl)4 with a mixture of PhNHNHPh and TolNHNHTol gives only the homodimers 1a and [Cp*RuCl(μ-NHTol)]2 (Tol = p-tolyl). The lack of crossover indicates that cleavage of the hydrazine N−N bond is an intramolecular process. In polar solvents such as acetonitrile, the Ci dimer 1a isomerizes to the C2v isomer 1b, in which the anilido substituents are cis across the Ru2N2 core. Both isomers appear to be kinetic products of the synthesis, but 1b isomerizes to 1a in the benzene solvent. In the presence of 1a, 1,2-diphenylhydrazine disproportionates into azobenzene and aniline, and labeling studies show that this occurs without participation of the anilido ligands of 1a. Complex 1a shows slow exchange of the anilide ligands with toluidine (H2NTol) by NMR spectroscopy and is unreactive toward methanol, triethylphosphine, styrene, and phenylacetylene. The addition of silver triflate and phenylacetylene to 1a leads to a new species, assigned as the acetylene complex [{Cp*Ru(μ-NHPh)}2(μ-η2:η2-PhC⋮CH)](OTf)2 (6a)." @default.
- W1998399592 created "2016-06-24" @default.
- W1998399592 creator A5018364473 @default.
- W1998399592 creator A5037787121 @default.
- W1998399592 creator A5056844262 @default.
- W1998399592 creator A5076740802 @default.
- W1998399592 date "2007-06-01" @default.
- W1998399592 modified "2023-10-17" @default.
- W1998399592 title "Synthesis and Reactivity of a Ruthenium(III) Bis(anilide) Dimer by Oxidative Addition of an N,N‘-Disubstituted Hydrazine" @default.
- W1998399592 cites W1965425164 @default.
- W1998399592 cites W1967322338 @default.
- W1998399592 cites W1970482531 @default.
- W1998399592 cites W1971755287 @default.
- W1998399592 cites W1975918639 @default.
- W1998399592 cites W1978108869 @default.
- W1998399592 cites W1978238317 @default.
- W1998399592 cites W1979514772 @default.
- W1998399592 cites W1979680045 @default.
- W1998399592 cites W1983166440 @default.
- W1998399592 cites W1984892528 @default.
- W1998399592 cites W1984916601 @default.
- W1998399592 cites W1984919019 @default.
- W1998399592 cites W1985669906 @default.
- W1998399592 cites W1986275822 @default.
- W1998399592 cites W1987777022 @default.
- W1998399592 cites W1991280887 @default.
- W1998399592 cites W1997740585 @default.
- W1998399592 cites W1998398214 @default.
- W1998399592 cites W2004200148 @default.
- W1998399592 cites W2007090087 @default.
- W1998399592 cites W2007354416 @default.
- W1998399592 cites W2008066757 @default.
- W1998399592 cites W2012425993 @default.
- W1998399592 cites W2018284758 @default.
- W1998399592 cites W2018350102 @default.
- W1998399592 cites W2020856752 @default.
- W1998399592 cites W2021318608 @default.
- W1998399592 cites W2023071257 @default.
- W1998399592 cites W2034741711 @default.
- W1998399592 cites W2036060151 @default.
- W1998399592 cites W2037597083 @default.
- W1998399592 cites W2042408408 @default.
- W1998399592 cites W2047266651 @default.
- W1998399592 cites W2053066220 @default.
- W1998399592 cites W2061830719 @default.
- W1998399592 cites W2065997738 @default.
- W1998399592 cites W2068525315 @default.
- W1998399592 cites W2069319233 @default.
- W1998399592 cites W2072771717 @default.
- W1998399592 cites W2074486892 @default.
- W1998399592 cites W2075558639 @default.
- W1998399592 cites W2077187637 @default.
- W1998399592 cites W2078741254 @default.
- W1998399592 cites W2079689329 @default.
- W1998399592 cites W2083823893 @default.
- W1998399592 cites W2084189843 @default.
- W1998399592 cites W2085057349 @default.
- W1998399592 cites W2088530348 @default.
- W1998399592 cites W2088761526 @default.
- W1998399592 cites W2092240706 @default.
- W1998399592 cites W2094220711 @default.
- W1998399592 cites W2104159745 @default.
- W1998399592 cites W2120100171 @default.
- W1998399592 cites W2122754842 @default.
- W1998399592 cites W2141898554 @default.
- W1998399592 cites W2142340513 @default.
- W1998399592 cites W2157590568 @default.
- W1998399592 cites W2161324136 @default.
- W1998399592 cites W2168837553 @default.
- W1998399592 cites W2334547693 @default.
- W1998399592 cites W2949322914 @default.
- W1998399592 cites W2950036044 @default.
- W1998399592 cites W2951507411 @default.
- W1998399592 cites W2952662985 @default.
- W1998399592 cites W4255088456 @default.
- W1998399592 cites W4319688299 @default.
- W1998399592 doi "https://doi.org/10.1021/om0700462" @default.
- W1998399592 hasPublicationYear "2007" @default.
- W1998399592 type Work @default.
- W1998399592 sameAs 1998399592 @default.
- W1998399592 citedByCount "22" @default.
- W1998399592 countsByYear W19983995922012 @default.
- W1998399592 countsByYear W19983995922013 @default.
- W1998399592 countsByYear W19983995922014 @default.
- W1998399592 countsByYear W19983995922015 @default.
- W1998399592 countsByYear W19983995922016 @default.
- W1998399592 countsByYear W19983995922017 @default.
- W1998399592 countsByYear W19983995922023 @default.
- W1998399592 crossrefType "journal-article" @default.
- W1998399592 hasAuthorship W1998399592A5018364473 @default.
- W1998399592 hasAuthorship W1998399592A5037787121 @default.
- W1998399592 hasAuthorship W1998399592A5056844262 @default.
- W1998399592 hasAuthorship W1998399592A5076740802 @default.
- W1998399592 hasConcept C155647269 @default.
- W1998399592 hasConcept C161790260 @default.
- W1998399592 hasConcept C178790620 @default.
- W1998399592 hasConcept C185592680 @default.
- W1998399592 hasConcept C21774173 @default.