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- W1998406856 abstract "The reactions of the hydroxo complexes [Mo(OH)(η3-methallyl)(CO)2(phen)] (1) and [Re(OH)(CO)3(Me2-bipy)] (2) (phen = 1,10-phenanthroline, Me2-bipy= 4,4‘-dimethyl-2,2‘-bipyridine) with maleic anhydride, phenyl(ethyl)ketene, diphenylketene, and rac-lactide afford new carboxylato complexes. The molybdenum and rhenium hydroxo complexes react in the same way, and their reactions are quantitative. The products, some of which have been characterized by X-ray diffraction, feature monodentate O-bonded carboxylato ligands, and their treatment with triflic acid yields the triflato complexes [Mo(OTf)(η3-methallyl)(CO)2(phen)] and [Re(OTf)(CO)3(Me2-bipy)] and the corresponding free carboxylic acid." @default.
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- W1998406856 date "2006-03-01" @default.
- W1998406856 modified "2023-10-16" @default.
- W1998406856 title "Reactivity of Molybdenum and Rhenium Hydroxo Complexes toward Organic Electrophiles: Reactions that Afford Carboxylato Products" @default.
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- W1998406856 doi "https://doi.org/10.1021/om051081g" @default.
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