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• W1998411021 abstract "A new trinuclear species containing a Ta(IV)–Ta(IV) bond, Ta3(μ-H)(μ-NMe2)(μNBut)2(NBut)(NMe2)5, has been formed by reductive elimination of H2. Ta2H2(μ-NMe2)2(NMe2)2(NBut)2 has also been isolated. O2 oxidizes the Ta(IV)–Ta(IV) bond to yield Ta3(μ3-O)(H)(μNBut)(μ-NMe2)2(NMe2)4(NBut)2 under ligand exchange. Delocalization of d electrons is discussed." @default.
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• W1998411021 date "2011-01-01" @default.
• W1998411021 modified "2023-10-18" @default.
• W1998411021 title "Unexpected formation of a trinuclear complex containing a Ta(iv)–Ta(iv) bond in the reactions of ButNTa(NMe2)3 with silanes" @default.
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• W1998411021 doi "https://doi.org/10.1039/c1cc12837j" @default.
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