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- W1998418603 abstract "The aggregation properties of metallic 2,9,6,23-tetrasulfophthalocyanines MTSPc (M=Fe, Co, Ni, Cu and Al) embedded in transparent monolithic gels of silica prepared by the sol–gel method have been followed by UV–Vis spectroscopy. These studies are necessary to follow the various complex stages of the hydrolysis–condensation reactions forming the monolithic gels. In view of the fact that under the experimental conditions used in this work (OH)AlTSPc does not show any agglomeration tendencies, it has been used as a label to determine the optimum conditions for the inclusion of the MTSPc molecules. Dimethyl formamide (DMF) and pyridine (py) have been selected as agglomeration control agents. The utilization of DMF gives materials less prone to fracture and of better optical properties than those obtained by the use of pyridine. In the case of CuTSPc and CoTSPc species with DMF (4% v/v) some color fading in the gels was observed." @default.
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- W1998418603 date "2000-11-01" @default.
- W1998418603 modified "2023-10-12" @default.
- W1998418603 title "Aggregation properties of metallic tetrasulfophthalocyanines embedded in sol–gel silica" @default.
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- W1998418603 doi "https://doi.org/10.1016/s0277-5387(00)00575-1" @default.
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