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- W1998436145 abstract "TMG-chitotriomycin, a potent and selective inhibitor of the beta-N-acetylglucosaminidases that possesses an unique N,N,N-trimethyl-d-glucosamine (TMG) residue, is revised to be the TMG-beta-(1-->4)-chitotriose instead of the originally proposed alpha-anomer via its total synthesis, for which a highly convergent approach was developed in which the sterically demanding (1-->4)-glycosidic linkages are efficiently constructed by the Au(I)-catalyzed glycosylation protocol with glycosyl o-hexynylbenzoates as donors." @default.
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- W1998436145 date "2009-08-07" @default.
- W1998436145 modified "2023-09-23" @default.
- W1998436145 title "Total Synthesis and Structural Revision of TMG-chitotriomycin, a Specific Inhibitor of Insect and Fungal β-<i>N</i>-Acetylglucosaminidases" @default.
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- W1998436145 doi "https://doi.org/10.1021/ja9055245" @default.
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