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- W1998481574 abstract "A poly(isobutylene-b-styrene) (PIB-PS) copolymer was synthesized via quasi-living carbocationic polymerization from an initiator containing a latent site for atom transfer radical polymerization (ATRP) initiation. The initiator, 3,3,5-trimethyl-5-chlorohexyl acetate (TMCHA), was synthesized in four steps from methyl 3,3-dimethyl-4-pentenoate. The PIB block was created at −70 °C in a methylcyclohexane/methyl chloride (60:40) cosolvent system, using TiCl4 as the catalyst, followed by sequential addition of styrene. The acetate head group of the resulting block copolymer was converted to a hydroxyl group using a strong base and subsequently esterified with 2-bromopropionyl bromide to create an initiating site for ATRP of tert-butyl acrylate, which was carried out using a Cu(I)Br/1,1,4,7,7,-pentamethyl-diethylenetriamine (PMDETA) catalyst system. The final terpolymers had compositions that were very close to theoretical." @default.
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- W1998481574 date "2006-03-01" @default.
- W1998481574 modified "2023-10-07" @default.
- W1998481574 title "Poly(tert-butyl acrylate-b-isobutylene-b-styrene) terpolymer from a carbocationic initiator containing a latent radical initiating site" @default.
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- W1998481574 doi "https://doi.org/10.1016/j.polymer.2006.01.048" @default.
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